2024
Tsuji-Trost based cascades: From Passerini adducts of cinnamaldehyde to allylated oxazolones.
Elmamouni, E.; Guillard, M.; Haddou, B.; Grimaud, L.; El Kaim, L.
J. Org. Chem. 2024, accepted.
2023
Electrophotocatalysis: taking the best from the two worlds. Vitale, M.R.; Lahkdar, S.; Grimaud, L. Curr. Opin. Electro. 2023, 40, 101307. DOI: 10.1016/j.coelec.2023.101307.
We Already Know Everything about Oxidative Addition to Pd(0) – Do We? Rio, J.; Liang, H.; Perrin, M. E.; Perego, L.; Grimaud, L.; Payard, P. A. ACS Cat. 2023, 2023, 13, 17, 11399–11421. DOI: 10.1021/acscatal.3c01943.
Efficient and scalable synthesis of 6,6-dimethyl-3-oxabicyclo[3.1.0]hexan-2-one through organocatalyzed desymmetrization and chemoselective reduction. Tintori, G.; Jacob, C.; Delsarte, C.; Potié, F.; Grimaud, L.; Vitale, M.; Echeverria, P. G. Synthesis 2023, accepted. DOI: 10.1055/a-2217-0996
Regime Switch in the Dual-Catalyzed Coupling of Alkyl Silicates with Aryl Bromides. Jaouadi, K.; Abdellaoui, M.; Levernier, E.; Payard, P. -A.; Derat, E.; Le Saux, T.; Ollivier, C.; Torelli, S.; Jullien, L.; Plasson, R.; Fensterbank, L.; Grimaud, L. Chem. Eur. J. 2023, e202301780. DOI: 10.1002/chem.202301780.
Assessing the extent of potential inversion by cyclic voltammetry: theory, pitfalls, and application to a nickel complex with redox-active iminosemiquinone ligands. Hessin, C.; Schleinitz, J.; Le Breton, N.; Choua, S.; Grimaud, L.; Fourmond, V.; Desage-El Murr, M.; Leger, C. Inorg. Chem. 2023, 62, 8, 3321–3332. DOI : 10.1021/acs.inorgchem.2c04365
A Mn(OAc)3 triggered formation of cyclopropanes from Ugi adducts. El Kaim, L.; Grimaud, L.; Vitale, M.; Cheibas, C.; Vieu, E.; Casaretto, N. Synlett 2023, 2023, 34, 1581-1586. DOI: 10.1055/a-2005-5220
2022
Redox Control of Particle Deposition from Drying Drops. Galy, P. E.; Guitton-Spassky, T.; Sella, C.; Thouin, L.; Vitale, M. R.; Baigl, D. ACS Appl. Mater. Interfaces 2022, 14, 3374–3384. DOI: 10.1021/acsami.1c18933
Copper-Catalyzed Homocoupling of Boronic Acids: A focus on B-to-Cu and Cu-to-Cu Transmetalations. Salamé, A.; Rio, J.; Ciofini, I.; Perrin, L.; Grimaud, L.; Payard, P. -A. Molecules 2022, 27(21), 7517-7531. doi: 10.3390/molecules27217517
Machine Learning Yield Prediction from NiCOlit, a Small-Size Literature Dataset of Nickel Catalyzed C-O Couplings. Schleinitz, J.; Langevin, M.; Smail, Y.; Wehnert, B.; Grimaud, L.; Vuilleumier, R. J. Am. Chem. Soc., 2022, 144, 14722–14730. DOI 10.1021/jacs.2c05302
From FFN dual probe screening to ITO microdevice for exocytosis monitoring: electrochemical and fluorescence requirements. Pandard, J.; Pan, N.; Ait-Yahiatène, E.; Grimaud, L.; Lemaître, F.; Guille-Collignon, M. ChemPhysChem 2022, 9, e202200321.DOI : 10.1002/celc.202200321
A single bioinspired hexameric nickel catechol-alloxazine catalyst combines metal and radical mechanisms for alkene hydrosilylation. Das, A.; Schleinitz, J.; Karmazin, L.; Vincent, B.; Le Breton, N.; Guenet, A.; Choua, S.; Grimaud, L.; Desage-El Murr, M. Chem. Eur. J. 2022, 28, e202200596. DOI 10.1002/chem.202200596.
Electrochemical Benzylic CH Functionalization with Isocyanides. Tang, S.; Guillot, R.; Grimaud, L.; Vitale, M. R.; Vincent, G. Org. Lett. 2022, 24, 2125-2130. DOI: 10.1021/acs.orglett.2c00364
Impact of the capping agent removal from Au NPs@MOF core-shell nanoparticles heterogeneous catalysts. Dai, S.; Phung Ngoc, K.; Grimaud, L.; Zhang, S.; Tissot, A.; Serre, C. J. Mat. Chem. A 2022, 10, 3201-3205.
In Situ Formation of Cationic π-Allylpalladium Precatalysts in Alcoholic Solvents: Application to C–N Bond Formation. Steinsoultz, P.; Bailly, A.; Wagner, P.; Oliva, E.; Schmitt, M.; Grimaud, L.; Bihel, F. ACS Catal. 2022, 1, 560–567. DOI: 10.1021/acscatal.1c04641.
2021
A hybrid bioinspired catechol-alloxazine triangular nickel complex stabilizing protons and electrons. Das, A.; Jobelius, H.; Schleinitz, J.; Gamboa-Ramírez, S.; Creste, G.; Kervern, G.; Raya, J.; Le Breton, N.; Guenet, A.; Boubegtiten, Z.; Grimaud, L.; Orio, M.; Rogez, G.; Hellwig, P.; Choua, S.; Ferlay, S.; Desage-El Murr, M. Inorg. Chem. Frontiers 2021, 8, 5286-5298. doi: 10.1039/D1QI01131F
Finding Adapted Quinones for Harvesting Electrons from Photosynthetic Algae Suspensions. Sayegh, A.; Perego, L. A.; Romero, M. A.; Escudero, L.; Delacotte, J.; Guille-Collignon, M.; Grimaud, L.; Bailleul, B.; Lemaître, F. ChemElectroChem 2021, 8, 2968-2978.
Iron(II)-catalyzed intermolecular aziridination of alkenes employing hydroxylamine derivatives as clean nitrene sources. Kirby, G.; Grimaud, L.; Vitale, M.; Prestat, G.; Berhal, F. Green Chem. 2021, 23, 9428–9432. DOI: 10.1039/D1GC03495B.
Electrochemical TEMPO-Catalyzed Oxidative Ugi-Type Reaction. Pan, N.; Lee, M. X.; Bunel, L.; Grimaud, L.; Vitale, M. ACS Organic & Inorganic Au 2021, 1, 18-22. DOI : 10.1021/acsorginorgau.1c00003
Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts. Sallio, R.; Payard, P.-A.; Pakulski, P.; Diachenko, I.; Fabre, I.; Berteina-Raboin, S.; Colas, C. ; Ciofini, I.; Grimaud, L.; Gillaizeau, I. RSC Adv., 2021, 11, 15885-15889. DOI: 10.1039/d1ra02305e.
Metal-Free Deoxygenation of Amine N–Oxides: Synthetic and Mechanistic Studies. Lecroq, W.; Schleinitz, J. ; Billoue, M.; Perfetto, A. ; Gaumont, A. C.; Lalevée, J.; Ciofini, I.; Grimaud, L.; Lakhdar, S. ChemPhysChem 2021, 22, 1237-1242. DOI: 10.1002/cphc.202100108R2.
On the Role of Dppf Monoxide in the Transmetalation step of the Suzuki-Miyaura Coupling reaction. Payard, P.-A.; Bohn, A.; Tocqueville, D.; Jaouadi, K.; Escoude, E.; Ajig, S.; Dethoor, A.; Gontard, G.; Perego, L. A.; Vitale, M.; Ciofini, I.; Wagschal, S.; Grimaud, L. Organometallics 2021, 40, 1120−1128. DOI: 10.1021/acs.organomet.1c00090.
Phenyl Silicates with Substituted Catecholate Ligands: Synthesis, Structural Studies and Reactivity. Levernier, E.; Jaouadi, K.; Zhang, H. -R.; Corcé, V.; Bernard, A.; Gontard, G.; Troufflard, C.; Grimaud, L.; Derat, E.; Ollivier, C.; Fensterbank, L. Chem. Eur. J. 2021, 27, 8782-8790. DOI : 10.1002/chem.202100453.
2020
Cyclopropyl Thioethers, New Inputs for Palladium Catalyzed Ring Opening of Cyclopropanes. Ponra, S.; Nyadanu, A.; Pan, N.; Martinand-Lurin, E.; Savy, A.; Vitale, M. R.; El Kaim, L.; Grimaud, L. Org. Process Res. Dev. 2020, 24, 827–834. doi 10.1021/acs.oprd.9b00444
Preparation of Chiral Photosensitive Organocatalysts and Their Application for the Enantioselective Synthesis of 1,2-Diamines. Lyu, J.; Claraz, A.; Vitale, M. R.; Allain, C.; Masson, G. J. Org. Chem. 2020, 85, 12843–12855. DOI 10.1021/acs.joc.0c01931
Copper(I)-Catalyzed Dearomative (3+2) Cycloaddition of 3-Nitroindoles with Propargylic Nucleophiles: An Access to Cyclopenta[b]Indolines. Ling, J.; Mara, D.; Roure, B.; Laugeois, M.; Vitale, M. R. J. Org. Chem.2020, 85, 3838–3848. DOI 10.1021/acs.joc.9b03459
A DFT Protocol for the Prediction of 31P NMR Chemical Shifts of Phosphine Ligands in First-Row Transition Metal Complexes. Payard, P. A.; Perego, L. P.; Grimaud, L.; Ciofini, I. Organometallics 2020, 39, 17, 3121–3130. DOI: 10.1021/acs.organomet.0c00309.
Reversing reactivity: stereoselective desulfurative β-O-glycosylation of anomeric thiosugars with carboxylic acids under copper or cobalt catalysis. Bennai, N.; Chabrier, A.; Fatthalla, M.; Tran, C.; Yen-Pon, E. Belkadi, M.; Alami, M.; Grimaud, L.; Messaoudi, S. J. Org. Chem. 2020, 85, 8893-8909.
Rational Design of Lewis-Acid Catalysts for Direct Alcohol Amination, Part 2 – Titanium Triflimide as New Active Catalyst. Payard, P. A.; Finidori, C.; Guichard, L.; Cartigny,D.; Corbet, M.; Khrouz, L.; Bonneviot, L.; Wischert, R.; Grimaud, L.; Pera-Titus, M. Eur. J. Org. Chem. 2020, 3225-3228. DOI: 10.1002/ejoc.202000413.
Rational Optimization of Lewis-Acid Catalysts for the Direct Amination of Alcohols, Part 1 – Activity Descriptors for Metal Triflates and Triflimides. Payard, P. A.; Finidori, C.; Guichard, L.; Cartigny,D.; Corbet, M.; Khrouz, L.; Bonneviot, L.; Wischert, R.; Grimaud, L.; Pera-Titus, M. Eur. J. Org. Chem. 2020, 3219-3224. DOI: 10.1002/ejoc.202000229R1.
Iron Triflate Salts as Highly Active Catalysts for the Solvent-Free Oxidation of Cyclohexane. Payard, A.; Zheng, Y. -T.; Zhou, W. -J.; Khrouz, L.; Bonneviot, L.; Wischert, R.; Grimaud, L.; Pera-Titus, M. Eur. J. O. C. 2020, 3552-3559 . DOI: 10.1002/ejoc.202000263.
Copper Reactivity Can Be Tuned to Catalyze the Stereoselective Synthesis of 2‑Deoxyglycosides from Glycals. Palo-Nieto, C.; Sau, A.; Jeanneret, R; Payard, P.A.; Salamé, A.; Braga Martins-Teixeira, M.; Carvalho, I.; Grimaud, L.; Galan, M. C. Org. Lett. 2020, 22, 1991–1996. DOI: 10.1021/acs.orglett.9b04525.
2019
Electrochemical TEMPO-Catalyzed Multicomponent C(sp3)-H α-Carbamoylation of Free Cyclic Secondary Amines. Pan, N.; Ling, J.; Zapata, R.; Pulicani, J.-P.; Grimaud, L.; Vitale, M. R. Green Chem. 2019, 21, 6194-6199. DOI: 10.1039/C9GC03173A.
A Fluorescent False Neurotransmitter as a Dual Electrofluorescent Probe for Secretory Cell Models. Pandard, J.; Pan, N.; Ebene, D. H.; Le Saux, T.; Ait-Yahiatène, E.; Liu, X.; Grimaud, L.; Buriez, O.; Labbé, E.; Lemaître, F.; Guille-Collignon, M. ChemPlusChem 2019, 84, 1578–1586. DOI: 10.1002/cplu.201900385
Formation and Reactivity of XPhos-Ligated Palladium(0) Complexes in Oxidative Additions. Wagschal, S.; Perego, L. A.; Simon, A.; Franco-Espejo, A.; Tocqueville, C.; Albaneze-Walker, J.; Jutand, A.; Grimaud, L. Chem. Eur. J. 2019, 25, 6980-6987. DOI: 10.1002/chem.201900451
Copper-Catalysed Hydroamination of N-Allenyl Sulfonamides: The Key Role of Ancillary Coordinating Groups. Blieck, R.; Perego, L. A.; Ciofini, I.; Grimaud, L.; Taillefer, M.; Monnier F. Synthesis 2019, 51, 1225-1234. DOI:10.1055/s-0037-1611673
Electroactive fluorescent false neurotransmitter FFN102 partially replaces dopamine in PC12 cell vesicles. Hu, L.; Savy, A.; Grimaud, L.; Guille-Collignon, M.; Lemaître, F.; Amatore, C.; Delacotte, J. Biophys. Chem. 2019, 245, 1-5. DOI: 10.1016/j.bpc.2018.11.001
From Benzofurans to Indoles: Palladium-Catalyzed Reductive Ring-Opening and Closure via β-Phenoxide Elimination. Perego, L. A.; Wagschal, S.; Grüber, R.; Fleurat-Lessard, P.; El Kaïm, L.; Grimaud, L. Adv. Synth. Cat. 2019, 361, 151-159. DOI: 10.1002/adsc.201801225
2018
Palladium(0)-Catalyzed Diastereoselective (3+2) Cycloadditions of Vinylcyclopropanes with Sulfonyl-Activated Imines. Ling, J.; Laugeois, M.; Ratovelomanana-Vidal, V.; Vitale, M. R. Synlett 2018, 29, 2288–2292. DOI: 10.1055/s-0037-1609625
Palladium(0)-Catalyzed Dearomatization of 2-Nitrobenzofurans Through Formal (3+2) Cycloadditions with Vinylcyclopropanes: a Straightforward Access to Cyclopenta[b]benzofurans. Ling, J.; Laugeois, M.; Michelet, V.; Ratovelomanana-Vidal, V.; Vitale, M. R. Synlett 2018, 29, 928–932. DOI : 10.1055/s-0036-1591540
Metformin reveals a mitochondrial copper addiction of mesenchymal cancer cells. Müller, S.; Versini, A.; Sindikubwabo, F.; Belthier, G.; Niyomchon, S.; Pannequin, J.; Grimaud, L.; Cañeque, T.; Rodriguez R. PLOS ONE 2018, 13, e020676. DOI: 10.1371/journal.pone.0206764.
Direct Amination of Alcohols Catalyzed by Aluminum Triflate: an Experimental and Computational Study. Payard, P. A.; Gu, Q.; Guo, W.; Wang, Q.; Corbet, M.; Michel, C.; Sautet, P.; Grimaud, L.; Wischert, R.; Pera‐Titus, M. Chem. Eur. J. 2018, 53, 14146-14153. DOI 10.1002/chem.201801492.
Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: a Mechanistic Focus on Boron-to-Nickel Transmetalation. Payard, P. A.; Perego, L. A.; Ciofini, I.; Grimaud, L. ACS catal. 2018, 8, 4812–4823. DOI: 10.1021/acscatal.8b00933
4-Aminopyrimidine Libraries from the Ugi-Smiles Reaction of Thiouracil. Ait Sidhoum, M.; El Kaïm, L.; Grimaud, L. Tetrahedron 2018, 74, 5222-5231. DOI 10.1016/j.tet.2018.04.058.
Coupling electrochemistry and TIRF-microscopy with the fluorescent false neurotransmitter FFN102 supports the fluorescence signals during single vesicle exocytosis detection. Liu, X.; Hu, L.; Pan, N.; Grimaud, L.; Labbé, E. ; Buriez, O.; Delacotte, J.; Lemaître, F.; Guille-Collignon, M. Biophys. Chem. 2018, 235, 48-55. DOI: 10.1016/j.bpc.2018.02.004
Labelling of hyaluronic acids with a Re-tricarbonyl tag and percutaneous penetration into human skin studied by multimodal imaging. Henry, L.; Delsuc, N.; Laugel, C.; Lambert, F.; Sandt, C.; Hostachy, S.; Bernard, A. S.; Bertrand, H. C.; Grimaud, L.; Baillet-Guffroy, A.; Policar, C. Bioconjugate Chem. 2018, 29, 987–991. DOI: 10.1021/acs.bioconjchem.7b00825
Evidence for a Cooperative Mechanism Involving two Palladium(0) Centers in the Oxidative Addition of Iodoarenes. Perego, L. A.; Payard, P. A.; Haddou, B.; Ciofini, I.; Grimaud, L. Chem. Eur. J. 2018, 24, 2192-2199. DOI: 10.1002/chem.201704899
TiCl4-mediated synthesis of 3,4-hetero-disubstituted isocoumarins by means of isocyanide insertion reactions. Ponra, S.; Nyadanu, A.; Maurin, S.; El Kaïm, L.; Grimaud, L.; Vitale, M. R. Synthesis, 2018, 50, 1331-1342. DOI : 10.1055/s-0036-1591733
2017
Palladium(0)-Catalyzed Dearomative [3+2] Cycloaddition of 3-Nitroindoles with Vinylcyclopropanes: An Entry to Stereodefined 2,3-Fused Cyclopentannulated Indoline Derivatives. Laugeois, M.; Ling, J.; Ferard, C.; Michelet, V.; Ratovelomanana-Vidal, V.; Vitale, M. R.Org. Lett. 2017, 19, 2266–2269. DOI: 10.1021/acs.orglett.7b00784
Copper-Catalyzed Hydroamination of N-Allenylazoles: Access to Amino-Substituted N-Vinylazoles. Perego, L. A.; Blieck, R.; Michel, J.; Ciofini, I.; Grimaud, L.; Taillefer, M.; Monnier, F. Adv. Synth. Cat. 2017, 359, 4388–4392. DOI: 10.1002/adsc.201700965
Copper-Catalyzed Hydroamination of Allenes: from Mechanistic Understanding to Methodology Development. Perego, L. A.; Blieck, R.; Groué, A.; Monnier, F.; Taillefer, M.; Ciofini, I.; Grimaud, L. ACS Catal. 2017, 7, 4253−4264. DOI: 10.1021/acscatal.7b00911
Stereoselective access to trisubstituted fluorinated alkenyl thioethers. Fabre, I.; Poisson, T.; Pannecoucke, X.; Gillaizeau, I.; Ciofini, I.; Grimaud, L. Catal. Sci. Technol. 2017, 7, 1921-1927. DOI: 10.1039/C7CY00076F
N-N bond formation in Ugi Processes: from nitric acid to libraries of Nitramines. Mercalli, V.; Nyadanu, A.; Cordier, C.; Tron, G. C.; Grimaud, L.; El Kaim, L. Comm. 2017, 53, 2118-2121. DOI: 10.1039/C6CC10288C
A dual functional electroactive and fluorescent probe for coupled measurements of vesicular exocytosis with high spatial and temporal resolution. Liu, X.; Savy, A.; Maurin, S.; Grimaud, L.; Labbé, E.; Buriez, O.; Delacotte, J.; Amatore, C.; Lemaître, F.; Guille-Collignon, M. Angew. Chem. Int. Ed. 2017, 2366-2370. DOI: 10.1002/anie.201611145
Ugi-Smiles couplings of purine derivatives. Ben Abdessalem, A.; Abderrahim, R.; Dos Santos, A.; El Kaïm, L.; Grimaud, L. Synlett 2017, 28, 691–694. DOI: 10.1055/s-0036-1588117
2016
Asymmetric preparation of polysubstituted cyclopentanes by synergistic Pd(0)/amine catalyzed formal [3+2] cycloadditions of vinyl cyclopropanes with enals. Laugeois, M.; Ponra, S.; Ratovelomanana-Vidal, V., Michelet, V.; Vitale, M. R. Chem. Commun. 2016, 52, 5332-5335. DOI: 10.1039/c6cc01775d
Practical synthesis of polysubstituted naphthalene derivatives via HNTf2-catalyzed benzannulation reaction. Ponra, S.; Vitale, M. R.;* Michelet, V.; Ratovelomanana-Vidal, V. Arkivoc 2016, (ii), 62–81. DOI: 10.3998/ark.5550190.p009.219
Role of Fluoride Ions in Palladium-Catalyzed Cross-Coupling Reactions. Jutand, A.; Grimaud, L. Synthesis 2016, 49, 1182-1189.
Optimized Conditions for Passerini-Smiles Reactions and Applications to Benzoxazinone Syntheses. Martinand-Lurin, E.; Dos Santos, A.; Robineau, E.; Retailleau, P.; Dauban, P.; Grimaud, L.; El Kaïm, L. Molecules 2016, 16, 1257-1270.
TiCl4-Mediated Preparation of Thiophtalide Derivatives via Formal Thio-Passerini Reactions. Ponra, S.; Nyadanu, A.; El Kaïm, L.; Grimaud, L.; Vitale, M. R. Org. Lett. 2016, 18, 4060–4063.
Multiple Roles of Isocyanides in Imidoylative Palladium-Catalyzed Couplings – A Mechanistic Study. Perego, L. A.; Fleurat-Lessard, P.; El Kaïm, L.; Ciofini, I.; Grimaud, L. Chem. Eur J. 2016, 22, 15491-15500.
Antagonist Effect of Acetates in C-N bond formation with in situ generated diazonium salts: a combined theoretical and experimental study. Fabre, I.; Perego, L. A.; Bergès, J.; Ciofini, I.; Grimaud, L.; Taillefer, M. Eur J. Org. Chem. 2016, 5887–5896.
Mechanistic Studies on the Pd-Catalyzed Direct C5 Arylation of Imidazoles: the Fundamental Role of the Azole as a Ligand for Pd. Perego, L. A.; Grimaud, L.; Bellina, F. Adv. Synth. Cat. 2016, 358, 597-609.
2015
HNTf2-Catalyzed Regioselective Preparation of Polysubstituted Naphthalene Derivatives Through Alkyne-Aldehyde Coupling. Ponra, S.; Vitale, M. R.; Michelet, V.; Ratovelomanana-Vidal, V. J. Org. Chem.2015, 80, 3250–3257. DOI: 10.1021/acs.joc.5b00353
Hypervalent iodine-mediated synthesis of 1,2-dispirodienones: experimental and theoretical investigations. Hromjakova, T.; Retailleau, P.; Grimaud, L.; Gandon, V.; Chabaud, L.; Guillou, C. Eur. J. Org. Chem. 2015, 7494-7503.
Transition-Metal-Free alpha-Arylation of Enolizable Aryl Ketones and Mechanistic Evidence for a Radical Process. Pichette-Drapeau, M.; Fabre, I.; Grimaud, L.; Ciofini, I.; Ollevier, T.; Taillefer, M. Angew. Chem. Int. Ed. 2015, 54, 10587-10591.
2014
Synergistic Iron-and Amine-Catalysis in Carbocyclizations. Praveen, C.; Leveque, S.; Vitale, M. R.; Michelet, V.; Vidal, V. Synthesis 2014, 46, 1334–1338. DOI: 10.1055/s-0033-1338612
The Ugi-Smiles and Passerini-Smiles couplings: a story about phenols in Isocyanide based Multicomponent Reactions El Kaïm, L.; Grimaud, L. Eur. J. Org. Chem. 2014, 7749–7762.
Benzoxazinone synthesis via Passerini-Smiles couplings. Martinand-Lurin, E.; El Kaïm, L.; Grimaud, L. Tetrahedron Lett. 2014, 55, 5144-5146.
Kinetic Data on the Synergetic Role of Amines and Water in the Reduction of Phosphine Ligated-Palladium(II) to Palladium(0). Amatore, C.; El Kaïm, L.; Grimaud, L.; Jutand, A.; Meigné, A.; Romanov, G., Eur. J.O.C 2014, 4709-4713.
Three Roles for Fluoride Ions in Palladium-Catalyzed Hiyama Reactions: Transmetallation of ArPdFL2 by Ar’Si(OR)3. Amatore, C.; Grimaud, L.; Le Duc, G.; Jutand, A, Angew. Chem. Int. Ed. 2014, 53, 6982–6985.
Copper-Catalyzed Olefinic C-H Difluoroacetylation of Enamides. Caillot, G.; Dufour, J.; Belhomme, M. C.; Poisson, T.; Grimaud, L.; Pannecoucke, X.; Gillaizeau, I. Chem. Commun. 2014, 50, 5887-5890.
Nitrile synthesis through catalyzed cascades involving acid-nitrile exchange reaction. Cartigny,D.; El Kaïm, L.; Grimaud, L.;* Marion, P; Jacquot, R. Synthesis 2014, 46, 1802-1806.
Double Smiles rearrangement of Passerini adducts towards benzoxazinones. Martinand-Lurin, E.; Dos Santos, A.; El Kaïm, L.; Grimaud, L.; Retailleau, P. Chem. Comm. 2014, 50, 2214-2217.