A new strategy for simulation of electrochemical mechanisms involving acute reaction fronts in solution: Application to model mechanisms

Printer-friendly version
TitleA new strategy for simulation of electrochemical mechanisms involving acute reaction fronts in solution: Application to model mechanisms
Publication TypeJournal Article
Year of Publication2010
AuthorsAmatore, C, Klymenko OV, Svir I
JournalElectrochemistry Communications
Volume12
Issue9
Pagination1165-1169
Date PublishedSep
ISBN Number1388-2481
Accession NumberISI:000281417200006
Abstract

The new strategy for adaptive simulation of electrochemical reaction mechanisms described in a previous paper (C. Amatore, O. Klymenko, I. Svir. Electrochem. Commun., (2010), doi:10.1016/j.elecom.2010.06.009) [1] provides an efficient method of obtaining accurate concentration distributions and electrochemical currents. In this paper, this strategy is illustrated and tested more deeply upon simulating several representative classical electrochemical mechanisms involving fast homogeneous comproportionation or disproportionation reactions that pose severe difficulties when simulated by classical finite difference methods including those based on exponentially expanding grids. (C) 2010 Elsevier B.V. All rights reserved.

URL<Go to ISI>://000281417200006
DOI10.1016/j.elecom.2010.06.008
Short TitleA new strategy for simulation of electrochemical mechanisms involving acute reaction fronts in solution: Application to model mechanisms
Unit: 
UMR 8640