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Ultrafast quantum dynamics of exciton dissociation at organic semiconductor junctions [Tamura, Ramon, Bittner, Burghardt, Phys. Rev. Lett. 100, 107402 (2008)] |
Current research directions focus on the theoretical description and simulation of quantum dynamical phenomena in systems of varying complexity, ranging from solute-solvent systems to chromophore-protein complexes and semiconducting polymers. While elementary quantum dynamical processes in small molecular systems have been analyzed in some detail over the past few decades, the interplay of such processes with structured and dynamically responding environments poses a considerable challenge. This is particularly manifest in ultrafast excited-state processes, where coherent quantum evolution is accompanied by the environment's non-equilibrium dynamics. Two examples from our recent work include the photophysics of organic semiconductor polymers, involving, in particular, exciton decay processes at donor-acceptor polymer heterojunctions [Tamura, Ramon, Bittner, Burghardt, Phys. Rev. Lett. 100, 107402 (2008)], and the excited-state processes in biological photosystems like rhodopsin and the Photoactive Yellow Protein [Gromov, Burghardt, Koeppel, Cederbaum, J. Am. Chem. Soc. 129, 6798 (2007)].
Our approach combines (i) quantum and mixed quantum-classical methods suitable for many dimensions, in particular multiconfigurational methods and quantum trajectory methods, with (ii) reduced-dimensionality models, for example effective-mode models for excited-state dynamics at high-dimensional conical intersection topologies [Cederbaum, Gindensperger, Burghardt, Phys. Rev. Lett. 94, 113003 (2005)]. A complementary strategy focuses on classical dynamical density functional theory (DDFT) for the description of nonequilibrium solvation. In [Burghardt, Bagchi, Chem. Phys. 329, 343 (2006)], we have proposed a new mixed quantum-classical approach which couples quantum molecular coordinates to a "generalized solvent coordinate", using a classical DDFT description of the solvent. This hybrid approach provides a promising tool for the study of elementary photochemical events in solution, and a generalization of our previous work in this area [Burghardt, Hynes, J. Phys. Chem. A, 110, 11411 (2006)].
Contact :
Irene Burghardt
irene.burghardt@ens.fr
tél : (33) (0) 1 44 32 33 38
fax : 33 97
Ecole Normale
Supérieure
Département de chimie
24 rue Lhomond
75231 PARIS CEDEX 05